Saturday 6 April 2013

Mentos and Coke: An Explosive Classroom Experiment


Fig 2: Mentos GeyserMany science experiments rely on a chemical reaction to produce the energy and gas required to create enough pressure for an explosion. These include the acid and carbonate reactions typical of simple volcano experiments and the 'elephant toothpaste' reactions where the decomposition of hydrogen peroxide into oxygen and water is catalysed. When such reaction mixtures are enclosed or confined to a restricted space, the pressure resulting from the build up of gaseous products causes an explosion.

In a chemical change, new products are formed. An example of this occurs when vinegar is added to sodium carbonate in traditional 'volcano' reactions. The new products formed in this case are carbon dioxide gas, water and sodium acetate, according to the equation below:

acetic acid (vinegar) + sodium carbonate ----> carbon dioxide + water + sodium acetate
Fig.1: Diet Coke and Mentos
When Mentos lollies are added to a carbonated drink such as Diet Coke, however, there are no new products formed. The rapid production of bubbles is instead a result of the dissolved carbon dioxide in the drink rapidly coming out of solution and forming a gas. As the gas bubbles expand, the pressure inside the bottle increases, resulting in a stream of foam shooting out through its narrow opening (see figure 1).
Why Do Mentos Lollies Cause This Explosive Reaction?
According to Steve Spangler, there are two main reasons for this rapid build up of carbon dioxide. Firstly, the gums and proteins from the Mentos coating help to break the surface tension of the water in the drink, which in turn allows the gas bubbles to escape more readily. Secondly, the many small pits on the surface of the Mentos lollies act as nucleation sites for carbon dioxide bubbles to gather in large numbers. When these two factors combine, massive amounts of foam are produced in a short space of time, creating explosive results.
Mentos and Diet Coke Experiment- Materials and Teaching Method
In this investigation students will compare the effects of plain (mint flavoured) Mentos lollies with coloured ones. The difference between these two types of lollies is their surface – the coloured ones are smooth and do not have the pitted surface typical of the plain variety. Diet Coke is usually used because it is more effective than ordinary Coke and results in a less 'sticky' clean up.
The following materials and equipment are required per group of around four students:
                2 x 1.25 litre bottles of Diet Coke
                1 packet mint Mentos
                1 packet flavoured Mentos
                2 test tubes
                2 pieces of card around 4 x 4 cm in size
                digital camera (optional)
Students should be instructed to copy down the following directions, which could be followed by a teacher-led explanation.
                Add the contents of each packet of Mentos to separate test tubes.
                Move outdoors and place the two bottles of Diet Coke next to each other on a flat surface.
                Unscrew the lids of each bottle and place the cardboard over the openings of each vessel.
                Invert the test tubes over the card. When ready, simultaneously pull the cardboard out from under each tube. Move back quickly.
                Compare the height of the fountain produced for each type of Mentos. If possible, record this with a digital camera.
The following questions could be written on the board after students write up the experiment and their observations:
1.             Which type of Mentos – plain or coloured- produced the biggest explosion?
2.             Can you suggest a reason for your observation?
3.             Explain why the experiment demonstrates a physical, rather than a chemical change.
4.             What aspects of the experiment did you control (that is, keep the same)?
Mentos and Diet Coke Experiment – Follow Up Activities
Students may wish to observe the effects of using Diet Coke compared to normal Coke or other carbonated drinks (as in figure 2). In this case, plain Mentos lollies should be used for each bottle. They could also experiment with other types of candy to find out if similar nucleation processes occur in these cases.
References
Muir, Hazel. "Science of Mentos-Diet Coke Explosions Explained." newscientist.com, 2008.
Spangler, Steve. "Mentos Diet Coke Geyser." stevespanglerscience.com, 2010.

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